Tris(dibenzylideneacetone)dipalladium(0) CAS 51364-51-3 Assay >97.0% Pd 20.9~21.9%

Short Description:

Name: Tris(dibenzylideneacetone)dipalladium(0)

Synonyms: Pd2(dba)3; Tris(dba)dipalladium(0) 

CAS: 51364-51-3

Assay: >97.0% 

Pd: 20.9~21.9%

Appearance: Black Powder 

E-Mail: alvin@ruifuchem.com


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Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer of Tris(dibenzylideneacetone)dipalladium(0) (CAS: 51364-51-3) with high quality. We can provide COA, worldwide delivery, small and bulk quantities available. Please contact: alvin@ruifuchem.com

Chemical Properties:

Chemical Name Tris(dibenzylideneacetone)dipalladium(0) 
Synonyms [Pd2(dba)3] x dba; Pd2dba3; Pd2(dba)3; Tris(dba)dipalladium(0); Bis[tris(dibenzylideneacetone)palladium(0)]
CAS Number 51364-51-3
CAT Number RF-PI2210
Stock Status In Stock 
Molecular Formula C51H42O3Pd2 
Molecular Weight 915.73  
Melting Point 152.0~155.0℃
Sensitive Light Sensitive, Air Sensitive, Moisture Sensitive
Water Solubility Insoluble in Water
Brand Ruifu Chemical

Specifications:

Item Specifications
Appearance Black Purple Powder
Assay >97.0% 
Palladium Content (Pd) 20.9~21.9% (ICP) 
Carbon by Elemental Analysis 64.6~69.2%
Total Metallic Impurities ≤1600ppm
A Single Impurity Content ≤100ppm
Infrared Spectrum Conforms to Structure
Proton NMR Spectrum Conforms to Structure
Test Standard Enterprise Standard
Shelf Life 24 Months

Package & Storage:

Package: Bottle, Drum, or according to customer's requirement

Storage Condition: Store in sealed containers at cool and dry place; Protect from light and moisture

Advantages:

1

FAQ:

Application:

Tris(dibenzylideneacetone)dipalladium(0), synonyms Pd2(dba)3, (CAS: 51364-51-3) is a cycloaddition catalyst, is the most widely used Pd0 precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. It is used as catalyst for a wide variety of Pd catalyzed reactions including Suzuki coupling, Heck coupling, Negishi coupling, Carroll reaarangement, Trost asymmetric allylic alkylation, Buchwald-Hartwig amination of acryl halides, fluorination of allylic chlorides, arylation of ketones, carbonylation of 1,1-dichloro-1-alkenes, ß-arylation of carboxylic esters, and conversion of aryl and vinyl triflates to aryl and vinyl halides. It is also involved in the synthesis of azepane. Tris(dibenzylideneacetone)dipalladium(0) is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors. Also used in the synthesis of polymer bulk-heterojunction solar sells as a semiconductor. Its worked related to trace metals basis, Asymmetric synthesis, Catalysis or catalyst, Coupling reactions, Cross couplings, Heck Reaction, Ligands,Organic synthesis,Suzuki coupling, Polymer science, Materials Chemistry, Column chromatography and Organic Compounds, and Arylations, Aminations, Deprotonations, Hydroxylations, Fluorinations. Catalyst precursor for conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics. Catalyst for the synthesis of epoxides. Catalytic asymmetric allylic and homoallylic diamination of terminal olefins. Site-selective benzylic sp3 palladium-catalyzed direct arylation. Palladium-catalyzed one-pot synthesis of tricyclic indolines. Active catalyst for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles. Catalyst in combination with BINAP for the asymmetric Heck Arylation of olefins. Precursor for palladium-catalyzed carbon-nitrigen bond formation. Catalyst for α-arylation of ketones. Cross-coupling of aryl halides with aryl boronic acids.

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