Potassium tert-Butoxide (KTB) CAS 865-47-4 Purity >99.0% (T)

Short Description:

Chemical Name: Potassium tert-Butoxide 

Synonyms: KTB

CAS: 865-47-4

Purity: >99.0% (Titration by HCl)

Appearance: White Powder 

Contact: Dr. Alvin Huang

Mobile/Wechat/WhatsApp: +86-15026746401

E-Mail: alvin@ruifuchem.com


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865-47-4 - Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer of Potassium tert-Butoxide (KTB) (CAS: 865-47-4) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, excellent service, small and bulk quantities available. Purchase Potassium tert-Butoxide, Please contact: alvin@ruifuchem.com

865-47-4 - Chemical Properties:

Chemical Name Potassium tert-Butoxide 
Synonyms KTB; Potassium tert-Butylate; Potassium tert-Butanolate; tert-Butanol (Potassium); PTB
Stock Status In Stock, Production Capacity 1500 Tons per Year
CAS Number 865-47-4
Molecular Formula C4H9KO
Molecular Weight 112.21 g/mol
Melting Point 256.0~258.0℃(dec.) (lit.)
Boiling Point 275℃ 
Density 0.910 g/mL at 20℃
Store Under Inert Gas Store Under Inert Gas
Sensitive Hygroscopic. Moisture Sensitive
Hydrolytic Sensitivity 7: Reacts Slowly with Moisture/Water
Solubility  Very Soluble in Tetrahydrofuran. Soluble in Ether. Very Slightly Hydrocarbons
COA & MSDS Available
Sample  Available
Place of Origin  Shanghai, China
Brand Ruifu Chemical

865-47-4 - Specifications:

Items Specifications  Results
Appearance White Powder  White Powder   
Potassium tert-Butoxide >99.0% (Titration by HCl) 99.6%
Free Alkali  <1.00% 0.4%
Potassium Carbonate <0.30% <0.30%
Infrared Spectrum Consistent with Structure Complies 
NMR Spectrum Consistent with Structure Complies
Conclusion The product has been tested and complies with the given specifications

Package/Storage/Shipping:

Package: Bottle, Aluminium foil bag, 25kg/Cardboard Drum, or according to customer's requirement.
Storage Condition: Keep the container tightly closed and store in a cool, dry and well-ventilated warehouse away from incompatible substances. Protect from light and moisture. Pay attention to prevention of fire and sunshine during the storage and transportation.
Shipping: Deliver to worldwide by air, by FedEx / DHL Express. Provide fast and reliable delivery. 

865-47-4 - Stability:

Stable, but reacts violently with water and acids, possibly leading to fire. Incompatible with water, acids, halogenated hydrocarbons, alcohols, strong oxidizing agents, ketones, carbon dioxide.   

Advantages:

Sufficient Capacity: Sufficient facilities and technicians

Professional Service: One stop purchasing service

OEM Package: Custom package and label available

Fast Delivery: If within stock, three days delivery guaranteed

Stable Supply: Maintain reasonable stock    

Technical Support: Technology solution available

Custom Synthesis Service: Ranged from grams to kilos

High Quality: Established a complete quality assurance system

FAQ:

How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com 

15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals.

Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc.

Advantages? Superior quality, affordable price, professional services and technical support, fast delivery.

Quality AssuranceStrict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc.

SamplesMost products provide free samples for quality evaluation, shipping cost should be paid by customers.

Factory AuditFactory audit welcome. Please make an appointment in advance.

MOQ? No MOQ. Small order is acceptable.

Delivery Time? If within stock, three days delivery guaranteed.

TransportationBy Express (FedEx, DHL), by Air, by Sea.

Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided.

Custom SynthesisCan provide custom synthesis services to best fit your research needs.

Payment TermsProforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc. 

865-47-4 - Risk and Safety:

Risk Codes R11 - Highly Flammable
R19 - May form explosive peroxides
R22 - Harmful if swallowed
R34 - Causes burns
R35 - Causes severe burns
R14 - Reacts violently with water
R20 - Harmful by inhalation
R36/37 - Irritating to eyes and respiratory system.
R37 - Irritating to the respiratory system
Safety Description S16 - Keep away from sources of ignition.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S7/9 -
S8 - Keep container dry.
S43A -
S33 - Take precautionary measures against static discharges.
S27 - Take off immediately all contaminated clothing.
S29 - Do not empty into drains.
UN IDs UN 3274 3/PG 2
WGK Germany 1
FLUKA BRAND F CODES 10-21
TSCA Yes
HS Code 2905199090
Hazard Note Flammable solid/Corrosive
Hazard Class 8
Packing Group I

865-47-4 - Application:

Potassium tert-Butoxide (KTB) (CAS: 865-47-4) is an important kind of organic base with its alkalinity being stronger than potassium hydroxide. Because of the induction effect of three methyl groups in the (CH3) 3CO-, Potassium tert-Butoxide has stronger alkalinity and activity than other potassium alkoxides, thus being a very excellent catalyst. In addition, as a kind of strong alkaline, Potassium tert-Butoxide is widely used in the organic synthesis of chemical, pharmaceutical, and pesticide such as trans-esterification, condensation, rearrangement, polymerization, loop opening and the production of heavy metal orthoester. Potassium tert-Butoxide can be used to catalyze the Michael addition reaction, Pinacol rearrangement reaction and Ramberg-Backlund rearrangement reaction. Potassium tert-Butoxide is used as a condensing agent, which can be used to catalyze Darzens condensation reaction and Stobbe condensation reaction. Potassium tert-Butoxide is also the most effective alkaline for traditional akloxide-haloform reaction generating dihalogenated carbene. Therefore, Potassium tert-Butoxide has attracted more and more attention from chemical, pharmaceutical, pesticide and other industries. As Potassium tert-Butoxide has such a wide application, the domestic and international demand for high purity potassium tert-butoxide is very large.
Potassium tert-Butoxide is used as a strong non-nucleophilic base in organic chemistry. It is widely used the condensation reaction, rearrangement and ring-opening reaction in organic synthesis. People generally apply tert-butanol solution. Potassium tert-Butoxide is a kind of organic alkaline corrosion products with strong moisture absorption property and should be sealed for storage. We need to pay attention to prevention of fire and sunshine during the storage and transportation. It should be stored in a cool, ventilated and dry place.

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