o-Phenylenediamine (OPD) CAS 95-54-5 Purity ≥99.5% (GC)

Short Description:

Chemical Name: o-Phenylenediamine

Synonyms: 1,2-Phenylenediamine; OPD

CAS: 95-54-5

Purity: ≥99.5% (GC)

White to Off-White to Light Brown Crystals or Flakes 

Contact: Dr. Alvin Huang

Mobile/Wechat/WhatsApp: +86-15026746401

E-Mail: alvin@ruifuchem.com


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95-54-5 - Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer of o-Phenylenediamine (OPD) (CAS: 95-54-5) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, excellent service, small and bulk quantities available. Purchase o-Phenylenediamine, Please contact: alvin@ruifuchem.com

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95-54-5 - Chemical Properties:

Chemical Name o-Phenylenediamine 
Synonyms 1,2-Phenylenediamine; 1,2-Diaminobenzene; 1,2-Benzenediamine; o-Benzenediamine; o-Diaminobenzene; OPD
Stock Status In Stock, Production Capacity 7000 Tons per Year
CAS Number 95-54-5
Molecular Formula C6H8N2
Molecular Weight 108.14 g/mol
Melting Point 99.0~103.0℃ 
Boiling Point 256.0~258.0℃
Flash Point 110℃
Density 1.27 g/cm3 
Sensitive Light Sensitive, Air Sensitive 
Water Solubility  Soluble in Water, 41 g/l 35℃
Solubility  Very Soluble in Ether, Chloroform, Alcohol. Soluble in Acetone, Benzene
Stability Stable. Incompatible with Strong Oxidizing Agents.
COA & MSDS Available
Sample  Available
Origin Shanghai, China
Brand Ruifu Chemical

95-54-5 - Specifications:

Items Specifications  Results
Appearance White to Off-White to Light Brown Crystals or Flakes  Complies      
Melting Point 99.0~103.0℃ 101.7~102.3℃       
Purity / Analysis Method ≥99.5% (HPLC) 99.9%
Water by Karl Fischer  ≤0.50% 0.21%
o-Chloroaniline ≤0.03% Complies  
o-Nitroaniline ≤0.03% Complies  
p-Phenylenediamine ≤0.03% Complies  
m-Phenylenediamine ≤0.03% Complies  
Total Impurities ≤0.50% Complies 
Infrared Spectrum Consistent with Structure Complies 
Conclusion The product has been tested and complies with the given specifications

Package/Storage/Shipping:

Package: Bottle, Aluminium foil bag, 25kg/Bag, 25kg/Cardboard Drum, or according to customer's requirement.
Storage Condition: Keep the container tightly closed and store in a cool, dry and well-ventilated warehouse away from incompatible substances. Protect from light and moisture.
Shipping: Deliver to worldwide by air, by FedEx / DHL Express. Provide fast and reliable delivery. 

Advantages:

Sufficient Capacity: Sufficient facilities and technicians

Professional Service: One stop purchasing service

OEM Package: Custom package and label available

Fast Delivery: If within stock, three days delivery guaranteed

Stable Supply: Maintain reasonable stock    

Technical Support: Technology solution available

Custom Synthesis Service: Ranged from grams to kilos

High Quality: Established a complete quality assurance system

FAQ:

How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com 

15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals.

Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc.

Advantages? Superior quality, affordable price, professional services and technical support, fast delivery.

Quality AssuranceStrict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc.

SamplesMost products provide free samples for quality evaluation, shipping cost should be paid by customers.

Factory AuditFactory audit welcome. Please make an appointment in advance.

MOQ? No MOQ. Small order is acceptable.

Delivery Time? If within stock, three days delivery guaranteed.

TransportationBy Express (FedEx, DHL), by Air, by Sea.

Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided.

Custom SynthesisCan provide custom synthesis services to best fit your research needs.

Payment TermsProforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc. 

95-54-5 - Risk and Safety:

Risk Codes R20/21 - Harmful by inhalation and in contact with skin.
R25 - Toxic if swallowed
R36 - Irritating to the eyes
R40 - Limited evidence of a carcinogenic effect
R43 - May cause sensitization by skin contact
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R68 - Possible risk of irreversible effects
Safety Description S28 - After contact with skin, wash immediately with plenty of soap-suds.
S36/37 - Wear suitable protective clothing and gloves.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 - This material and its container must be disposed of as hazardous waste.
S61 - Avoid release to the environment. Refer to special instructions / safety data sheets.
S1/2 - Keep locked up and out of the reach of children.
UN IDs UN 1673 6.1/PG 3
WGK Germany 3
RTECS SS7875000
FLUKA BRAND F CODES 8-10-23
TSCA Yes
HS Code 2921511000
Hazard Class 6.1
Packing Group III
Toxicity LD50 in rats (mg/kg): 1070 orally; 516 i.p., C. Burnett et al., J. Toxicol. Environ. Health 2, 657 (1977)

95-54-5 - Application:

o-Phenylenediamine (OPD) (CAS: 95-54-5) is the simplest aromatic diamine. There are three isomers, namely o-Phenylenediamine, m-Phenylenediamine and p-Phenylenediamine. o-Phenylenediamine's color is easy to change upon exposure to air, from white to yellow, brown, purple, and finally into black.
o-phenylenediamine has active chemical properties, being able to have condensation reaction with acid, aldehydes, ketones and other compounds, generating heterocyclic compounds; it can also have oxidation, condensation, substitution and diazotization reaction.
Phenylenediamine is used as a fluorescent indicator and chromatographic analysis reagent. It is used for the identification of copper, gold, iron, magnesium, vanadium, ammonia, hydrogen sulfide, sulfur dioxide and chromic oxide, etc., and manufacturing azo dyes, fur dyeing and photographic materials. , Printing and dyeing industry.
1. It can be used as a cationic dye intermediates, being the main raw material of pesticides, carbendazim and other fungicides.
2. It can be used as analytical reagent, fluorescent indicator, also used in organic and dye synthesis. It can be used as an important intermediate in the manufacture of other fine chemicals, pesticides, pharmaceuticals and dyes, pigments, and fungicides, vulcanization accelerators for rubber, developers for the photographic industry, fur dyes and hair dyes. It is also used in hair dye formulation, as a photographic developing agent, and in organic synthesis.
3. Phenylenediamine is the intermediate of fungicide carbendazim, methyl thiophanate, and thiabendazole, but also insecticides quinalphos intermediates.  

95-54-5 - Toxicity:

o-Phenylenediamine has moderate toxicity, often due to inhalation of dust or skin absorption caused by poisoning (the latter phenomenon mostly). Inhalation of dust can cause rhinitis, bronchitis, frequent fever, causing unique asthma and vagal nervous tension caused by the tracheal inflammation, can cause severe acute eczema and eczema. m-Phenylenediamine can cause methemoglobin changes, while the p-phenylenediamine can cause bronchial asthma, allergic dermatitis.

95-54-5 - Hazards & Safety Information:

Category Toxic substances
Toxicity classification highly toxic
Acute toxicity Oral-Rat LD50: 1070 mg/kg; Oral-mouse LD50: 366 mg/kg
Flammability hazardous characteristics it is flammable with heating releasing toxic aniline gases
Storage and transportation characteristics Treasury: ventilated, low-temperature and dry; store it separately from food raw materials for storage and transportation
Fire extinguishing agent mist water, carbon dioxide, sand

95-54-5 - Safety Profile:

Confirmed carcinogen. Poison by ingestion and intraperitoneal routes. Moderately toxic by subcutaneous route. Mildly toxic by skin contact. Mutation data reported. A pesticide and pharmaceutical. When heated to decomposition it emits toxic fumes of NOx. See also other phenylenediamine entries and AMINES

95-54-5 - Shipping:

UN1673 Phenylenediamines (o-, m-, p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.   

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