DPPE.NiCl2 CAS 14647-23-5 Assay ≥98.0% Ni ≥11.1%

Short Description:

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride

Synonyms: DPPE.NiCl2 

CAS: 14647-23-5

Assay (Element Analysis): ≥98.0% Ni:  ≥11.1%

Appearance: Orange-Red Crystal Powder

Contact: Dr. Alvin Huang

Mobile/Wechat/WhatsApp: +86-15026746401

E-Mail: alvin@ruifuchem.com


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14647-23-5 - Description:

Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer of [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride (DPPE.NiCl2) (CAS: 14647-23-5) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, excellent service, small and bulk quantities available. Purchase DPPE.NiCl2, Please contact: alvin@ruifuchem.com

14647-23-5 - Chemical Properties:

Chemical Name [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride 
Synonyms DPPE.NiCl2; [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II); Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II); Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II)
Stock Status In Stock, Commercial Production  
CAS Number 14647-23-5
Molecular Formula C26H24Cl2NiP2
Molecular Weight 528.02 g/mol
Melting Point 263.0~265.0℃(lit.)  
Water Solubility  Insoluble in Water 
COA & MSDS Available
Place of Origin  Shanghai, China
Brand Ruifu Chemical

14647-23-5 - Specifications:

Items Specifications  Results
Appearance Orange-Red Crystal Powder   Complies      
Assay (Element Analysis) ≥98.0% 98.4%
Ni:  ≥11.1% Ni=11.11%
Assay (Element Analysis) C: 59.14 Conforms
H: 4.58
Melting Point  263.0~265.0℃  263.0~264.0℃ 
Solvent   ≤0.50% 0.15% 
Infrared Spectrum Consistent with Structure Complies 
Conclusion The product has been tested and complies with the given specifications

Package/Storage/Shipping:

Package: Fluorinated Bottle, Aluminium foil bag, 25kg/Cardboard Drum, or according to customer's requirement.
Storage Condition: Keep the container tightly closed and store in a cool, dry (2~8℃) and well-ventilated warehouse away from incompatible substances. Protect from light and moisture. Moisture sensitive.
Shipping: Deliver to worldwide by air, by FedEx / DHL Express. Provide fast and reliable delivery. 

Advantages:

Sufficient Capacity: Sufficient facilities and technicians

Professional Service: One stop purchasing service

OEM Package: Custom package and label available

Fast Delivery: If within stock, three days delivery guaranteed

Stable Supply: Maintain reasonable stock    

Technical Support: Technology solution available

Custom Synthesis Service: Ranged from grams to kilos

High Quality: Established a complete quality assurance system

FAQ:

How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com 

15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals.

Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc.

Advantages? Superior quality, affordable price, professional services and technical support, fast delivery.

Quality AssuranceStrict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc.

SamplesMost products provide free samples for quality evaluation, shipping cost should be paid by customers.

Factory AuditFactory audit welcome. Please make an appointment in advance.

MOQ? No MOQ. Small order is acceptable.

Delivery Time? If within stock, three days delivery guaranteed.

TransportationBy Express (FedEx, DHL), by Air, by Sea.

Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided.

Custom SynthesisCan provide custom synthesis services to best fit your research needs.

Payment TermsProforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc. 

14647-23-5 - Risk and Safety:

Risk Codes R45 - May cause cancer
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R42/43 - May cause sensitization by inhalation and skin contact.
R40 - Limited evidence of a carcinogenic effect
Safety Description S53 - Avoid exposure - obtain special instructions before use.
S22 - Do not breathe dust.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 - Wear suitable protective clothing.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S52 - Not recommended for interior use on large surface areas.
WGK Germany 3
TSCA No
HS Code 2843 9000.99

14647-23-5 - Application:

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride (DPPE.NiCl2) (CAS: 14647-23-5), organometallic catalysts, Suzuki-Miyaura cross coupling reaction, transition metal catalysts, coupling polymerization catalysts. As a catalyst, used in organic synthesis such as C-C/C-N/C-O coupling reactions
DPPE.NiCl2 is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions-homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

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