Bis[2-(diphenylphosphino)phenyl] Ether (DPEPhos) CAS 166330-10-5 Purity >98.0% (HPLC)

Bis[2-(diphenylphosphino)phenyl] Ether (DPEPhos) (CAS: 166330-10-5), is an organophosphorus compound, is a type of organic phosphine ligand that has a wide range of applications in various fields of research and industry. DPEPhos has been has been extensively studied and proved to be a versatile and efficient ligand for various catalytic reactions.
DPEPhos has been used as a catalyst in the synthesis of various compounds, including amines, alcohols, and ketones. DPEPhos has also been used in the synthesis of organophosphorus compounds. DPEPhos has been studied for its potential use in the synthesis of pharmaceuticals, agrochemicals, specialty chemicals, and polymers. DPEPhos has a symmetric P,P-bidentate structure, which allows it to form stable complexes with transition metals.
DPEPhos has been used as a ligand for various catalytic reactions such as Suzuki-Miyaura cross-coupling, Sonogashira cross-coupling, and Heck coupling. DPEPhos has also been used in the asymmetric hydrogenation of various substrates and the Pd-catalyzed hydroarylation of alkynes. Its effectiveness and efficiency in these reactions make it a valuable tool in organic synthesis.
Reaction
Useful as a ligand in the Pd-catalyzed formation of diaryl amines.
Has been recently applied to the C3 benzylation of indoles.
Has been recently applied to the monoallylation of ammonia.
Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.
Ligand used in carbonylation of aryl iodides.
Ligand used in the direct C-H arylation of benzothiodiazoles.
Ligand used in stereo-retentive azacyclization of propargylic carbonates.
Ligand used in palladium catalyzed benzyne trimerization.
Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.
Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology.